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Chapter 99 · Part 1

CHEMICAL BONDING AND MOLECULAR STRUCTURE

30
Concepts
2
Formulae
15 min
Read time
Intermediate

What this chapter is about

Matter's diversity and properties fundamentally depend on how atoms combine. Chemical bonds—the forces holding atoms together—determine whether a substance is a hard diamond, flexible plastic, reactive gas, or stable salt. Understanding chemical bonding requires knowledge of how electrons are rearranged when atoms interact, how this rearrangement leads to different bond types, and how molecular geometry emerges from bonding patterns. From simple molecules like water and ammonia to complex protein structures, bonding explains both the existence and behavior of matter. This chapter explores the principles governing chemical bond formation, major bond types, theories of bonding, and how structure determines molecular properties.

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Learning objectives

  • 1Describe the bonds, Valence, Molecular Geometry, and Properties
  • 2Explain tYPES OF CHEMICAL BONDS
  • 3Explain ionic Bonding
  • 4Explain covalent Bonding
  • 5Explain coordinate Covalent Bond (Dative Bond)
  • 6Explain metallic Bonding

Your learning path

Introduction
Understanding Bonds, Valence, Molecular Geometry, and Properties
1. TYPES OF CHEMICAL BONDS
Ionic Bonding
Covalent Bonding
Coordinate Covalent Bond (Dative Bond)
Metallic Bonding
2. VALENCE ELECTRONS AND THE OCTET RULE
Valence Electrons
Activity
Worked Example
Summary
Quiz
Revision
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Key terms

CharacteristicsConceptMechanismFormationFormal chargesp hybridizationHydrogen bondingsp² hybridizationsp³ hybridizationDipole-dipole forcesLondon dispersion forcesModelRulesLinearLigandStatement
30Concepts
2Formulae
15Minutes